主族金属与过渡金属的成键的滚木综述（指只有文献堆积和锐评）不定期更新

开裤乐

首先是过渡金属羰基化合物和主族元素形成的一系列具有奇妙的成键的分子配合物，但这部分只能被基质分离等方式观测到：
[1] C. Chi, S. Pan, L. Meng, M. Luo, L. Zhao, M. Zhou, G. Frenking, ““Alkali Metal Covalent Bonding in Nickel Carbonyl Complexes ENi(CO)3−,”” Angewandte Chemie 2019, 131, 1746–1752.
[2] B. Ju, Z. Zhang, X. Kong, J. Zou, G. Li, H. Xie, L. Jiang, ““Photoelectron velocity map imaging spectroscopy of group 14 elements and iron tetracarbonyl anionic clusters MFe(CO)4− (M = Si, Ge, Sn),”” The Journal of Chemical Physics 2024, 160, 044307.
[3] H. Xie, J. Zou, Q. Yuan, H. Fan, Z. Tang, L. Jiang, ““Photoelectron velocity-map imaging and theoretical studies of heteronuclear metal carbonyls M Ni(CO)3− ( M = Mg, Ca, Al),”” The Journal of Chemical Physics 2016, 144, 124303.
[4] J. Wang, C. Chi, H. Hu, L. Meng, M. Luo, J. Li, M. Zhou, ““Triple Bonds Between Iron and Heavier Group 15 Elements in AFe(CO)3− (A=As, Sb, Bi) Complexes,”” Angew Chem Int Ed 2018, 57, 542–546.
[5] J.-Q. Wang, C. Chi, J.-B. Lu, L. Meng, M. Luo, H.-S. Hu, M. Zhou, J. Li, ““Triple bonds between iron and heavier group-14 elements in the AFe(CO)3− complexes (A = Ge, Sn, and Pb),”” Chem. Commun. 2019, 55, 5685–5688.
[6] C. Chi, J.-Q. Wang, H.-S. Hu, Y.-Y. Zhang, W.-L. Li, L. Meng, M. Luo, M. Zhou, J. Li, ““Quadruple bonding between iron and boron in the BFe(CO)3− complex,”” Nat Commun 2019, 10, 4713.
[7] G. Wang, J. Zhao, H. Hu, J. Li, M. Zhou, ““Formation and Characterization of BeFe(CO)4− Anion with Beryllium−Iron Bonding,”” Angewandte Chemie 2021, 133, 9420–9424.
[8] J. Wang, C. Chi, H. Hu, X. Li, M. Luo, J. Li, M. Zhou, ““Multiple Bonding Between Group 3 Metals and Fe(CO)3−,”” Angew Chem Int Ed 2020, 59, 2344–2348.

开裤乐

对于TM-LA双催化体系的研究，最早应该是Ni-B，逐渐扩展到LA=Al,Y等：
[1] J. Lin, Y. Li, Z. Ke, ““Feature Analysis in High-Dimensional Data: Structure–Activity Relationships of Lewis Acid–Transition-Metal Complex-Catalyzed H2 Activation,”” J. Phys. Chem. A 2023, 127, 4375–4387.
[2] Y. Li, C. Hou, J. Jiang, Z. Zhang, C. Zhao, A. J. Page, Z. Ke, ““General H2 Activation Modes for Lewis Acid–Transition Metal Bifunctional Catalysts,”” ACS Catal. 2016, 6, 1655–1662.
[3] N. Gorgas, A. J. P. White, M. R. Crimmin, ““Cooperative C–H Bond Activation by a Low-Spin d6 Iron–Aluminum Complex,”” J. Am. Chem. Soc. 2022, 144, 8770–8777.

开裤乐

NHC-主族元素配合物作为配体与过渡金属形成金属-金属键的例子，综述中大多为非金属或半金属，但也有Al作为Lewis酸配位、Ge与Sn使用孤对电子向过渡金属配位的例子：
[1] A. Doddi, M. Peters, M. Tamm, ““N-Heterocyclic Carbene Adducts of Main Group Elements and Their Use as Ligands in Transition Metal Chemistry,”” Chem. Rev. 2019, 119, 6994–7112.

开裤乐

Zintl化合物中的主族金属-过渡金属成键，常见于稳定的（芳香性的）主族金属Zintl团簇作为配体向过渡金属配位：
[1] C. Liu, I. A. Popov, Z. Chen, A. I. Boldyrev, Z.-M. Sun, ““Aromaticity and Antiaromaticity in Zintl Clusters,”” Chemistry – A European Journal 2018, 24, 14583–14597.
[2] J. E. McGrady, F. Weigend, S. Dehnen, ““Electronic structure and bonding in endohedral Zintl clusters,”” Chemical Society Reviews 2022, 51, 628–649.

开裤乐

以及我曾经收集过一些关于芳香性标准大讨论与历史决议的文章，有空放上来